William Hume-RotheryBorn 15 May 1899; died 27 Sep 1968 at age 69.British metallurgist, internationally known for his work on the formation of alloys and intermetallic compounds. During WW II, he supervised many government contracts for work on complex aluminium and magnesium alloys. He established that the microstructure of an alloy depends on the different sizes of the component atoms, the valency electron concentration, and electrochemical differences. Hume-Rothery rules are an empirical guide to when two metals are sufficiently similar to be completely miscible (form a single phase at all relative concentrations). They are: (1). Atomic radii no more than about 15% different. (2). Pure metals have the same crystal structure. (3). Atoms have similar electronegativities. (4). Atoms have the same valence. |
